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Asymmetric Synthesis of Dihydronaphthoquinones Containing Adjacent Stereocenters via a Sulfa-Michael Addition Triggered Ring-Expansion Approach

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https://figshare.com/articles/dataset/Asymmetric_Synthesis_of_Dihydronaphthoquinones_Containing_Adjacent_Stereocenters_via_a_Sulfa_Michael_Addition_Triggered_Ring_Expansion_Approach/2170765
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资源简介:
A novel asymmetric synthetic approach for the construction of enantioenriched functionalized dihydroquinones incorporating adjacent quaternary and tertiary stereocenters has been reported, in which enantioenriched 3-allylic phthalides engaged in an unprecedented sulfa-Michael addition-triggered stereoselective ring-expansion reaction, and furnished the desired sulfur-incoporated dihydronaphthoquinones with high stereoselectivity.
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2016-02-13
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