Asymmetric Synthesis of Dihydronaphthoquinones Containing Adjacent Stereocenters via a Sulfa-Michael Addition Triggered Ring-Expansion Approach
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https://figshare.com/articles/dataset/Asymmetric_Synthesis_of_Dihydronaphthoquinones_Containing_Adjacent_Stereocenters_via_a_Sulfa_Michael_Addition_Triggered_Ring_Expansion_Approach/2170765
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资源简介:
A novel
asymmetric synthetic approach for the construction of enantioenriched
functionalized dihydroquinones incorporating adjacent quaternary and
tertiary stereocenters has been reported, in which enantioenriched
3-allylic phthalides engaged in an unprecedented sulfa-Michael addition-triggered
stereoselective ring-expansion reaction, and furnished the desired
sulfur-incoporated dihydronaphthoquinones with high stereoselectivity.
创建时间:
2016-02-13



