A One-Dimensional Magnet Based on [MoIII(CN)7]4–

Self-assembly of the [MoIII(CN)7]4– anion and the MnII unit with a macrocyclic ligand results in the first example of a one-dimensional (1D) chain compound based on the heptacyanomolybdate, [Mn­(LN5C10)]2[Mo­(CN)7]·2H2O (LN5C10 = 1,4,7,10,13-pentaazacyclopentadecane). Because of the existence of the interchain magnetic coupling, long-rang magnetic ordering was observed in this compound.将[MoIII(CN)₇]⁴⁻配阴离子与带有大环配体的二价锰（MnII）单元进行自组装，成功获得了首例基于七氰合钼(III)的一维（1D）链状化合物[Mn(LN5C10)]₂[Mo(CN)₇]·2H₂O（其中LN5C10代表1,4,7,10,13-五氮杂环十五烷）。由于该化合物中存在链间磁耦合作用，因而展现出长程磁有序现象。