The Unusual Stability of Homoleptic Di- and Tetravalent Chromium Alkyls
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https://figshare.com/articles/dataset/The_Unusual_Stability_of_Homoleptic_Di-_and_Tetravalent_Chromium_Alkyls/3772473
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资源简介：
Reaction of CrCl3(THF)3 with 3 equiv of R−M [R = Me3CCH2 (a), Me3SiCH2 (b)] afforded
either the previously reported tetravalent homoleptic R4Cr (1a, b) [M = MgCl] or the
unprecedented divalent and tetranuclear homoleptic [R2Cr]4 (2b) [M = Li]. Both types of
compounds display a remarkable chemical inertness toward proton transfer agents but
readily react with ethylene.
创建时间：
2016-08-26
