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Manganese(III,IV) and Manganese(III) Oxide Clusters Trapped by Copper(II) Complexes

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NIAID Data Ecosystem2026-03-06 收录
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Reactions of quinquedentate Schiff base ligands with Mn and Cu ions afforded icosa- and hexadecanuclear mixed-metal clusters in which dinuclear CuII complexes trapped oxo-bridged [MnIII8MnIV4O12] and [MnIII6O6] cores, respectively. Maximum entropy method analysis for synchrotron X-ray diffraction data was used to determine the oxidation states of the Mn ions.

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2016-07-05
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