A Cationic Antimonite Chain Templated by Sulfate: [Sb6O74+][(SO42–)2]
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https://figshare.com/articles/dataset/A_Cationic_Antimonite_Chain_Templated_by_Sulfate_Sb_sub_6_sub_O_sub_7_sub_sup_4_sup_SO_sub_4_sub_sup_2_sup_sub_2_sub_/2495056
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资源简介：
An extended metal oxide possessing a cationic charge on the host has been synthesized by hydrothermal methods. The structure consists of 1D antimony oxide [Sb6O7]4+ chains with a new structural motif of four Sb atoms wide and unprotonated sulfate anions between the chains. The material was characterized by powder and single-crystal X-ray diffraction. Thermal behavior and chemical resistance in aqueous acidic conditions (pH ∼2) indicate a highly stable cationic material. The stability is attributed to the entirely inorganic composition of the structure, where 1D covalently extended chains are electrostatically bound to divalent anions.
创建时间：
2016-02-20
