Experimental verification of halomethyl carbinols synthesis from carbonyl compounds using a TiCl4-Mg bimetallic complex promoter

Table of Content of Supporting Information (PDF) for the article:[S.1] Modeling of the Mg powder and reagents[S.2] Reaction of Mg powder with CH2Br2[S.3] Reaction of Mg powder with Mg∷CH2Br2 complex and TiCl4[S.4] A model of the reaction of the solvent molecules with the Ti/Mg catalyst.[S.4.A] Inclusion of DBE to the TiCl3∷MgCH2Br2 bimetallic catalyst[S.4.B] Inclusion of DEE to the TiCl3∷MgBr2 bimetallic catalyst[S.4.C] Inclusion of 2,5-dihydrofuran to the TiCl3∷MgCH2Br2 bimetallic catalyst[S.5] A model of 1,2-dichloroethane reaction with the magnesium powder[S.6] A model of the reaction of benzaldehyde with Ti/Mg catalyst[S.7] Hydrobenzoin formation promoted by the Ti/Mg catalyst[S.8] A possible formation of 1-bromomethyl)benzyl alcohol[S.9]A cumulative stoichiometric reaction of hydrobenzoin formation[S.10] The solvent effect on the output of the reaction (E.5) in the main text[S.11] NMR spectra[S.12] HRMS and EA spectraZIP file contents:separate figures and a table from PDF file.