Design, Synthesis, and Crystallographic Studies of Neutral Platinum-Based Macrocycles Formed via Self-Assembly
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https://figshare.com/articles/dataset/Design_Synthesis_and_Crystallographic_Studies_of_Neutral_Platinum_Based_Macrocycles_Formed_via_Self_Assembly/3348184
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资源简介：
A series of neutral, platinum-based macrocycles was synthesized from rigid oxygen donor building
blocks via self-assembly. The combination of a platinum-based 60° acceptor unit 1 with several linear and
angular dicarboxylate bridging ligands afforded hitherto unknown neutral platinum-based supramolecular
triangles and rhomboids. In addition, a similar reaction of the diplatinum molecular clip 6 and three different
linear dicarboxylates led to the formation of neutral molecular rectangles. Most of the macrocycles were
characterized by X-ray single-crystal structure analysis, and, in all cases, NMR spectra were consistent
with the formation of single highly symmetrical species.
创建时间：
2004-03-03
