Total Synthesis of (+)-Pyrenolide D
收藏NIAID Data Ecosystem2026-03-10 收录
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https://figshare.com/articles/dataset/Total_Synthesis_of_-Pyrenolide_D/7130576
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资源简介：
An efficient approach
to stereoselective construction of a spiro-γ-lactone
core structure via BF3-promoted formal [3 + 2] annulation
of aldehydo-aldose derivatives with γ-methylene-γ-butyrolactone
has been developed. The spiro-γ-lactone derivative was then
used in an efficient total synthesis of (+)-pyrenolide D. The developed
chemistry paves the way for total synthesis of structurally diverse
natural products containing spiro-lactone cores.
创建时间：
2018-09-25
