Secondary Phosphinocarbyne and Phosphaisonitrile Complexes
收藏Figshare2016-02-16 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Secondary_Phosphinocarbyne_and_Phosphaisonitrile_Complexes/2224573
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The palladium-mediated reaction of [W(CBr)(CO)2(Tp*)] (Tp* = hydrotris(3,5-dimethylpyrazol-1-yl)borate) with primary phosphines PH2R (R = Ph, Cy) affords the secondary phosphinocarbyne complexes [W(CPHR)(CO)2(Tp*)], deprotonation of which provides the anionic phosphaisonitrile complexes [W(CPR)(CO)2(Tp*)]−, including the structurally characterized salt [W(CPPh)(CO)2(Tp*)][K(kryptofix)].
创建时间：
2016-02-16
