Harnessing Scorpionate Ligand Equilibria for Modeling Reduced Nickel Superoxide Dismutase Intermediates
收藏NIAID Data Ecosystem2026-03-06 收录
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资源简介：
Hydrotris(3-phenyl-5-methylpyrazoyl)boratonickel(II) complexes with organoxanthate or dithiocarbamate coligands equilibrate between κ2- and κ3-chelation modes of the scorpionate ligand in solution, connecting N2S2 square-planar and N3S2 pyramidal ligand fields and a spin crossover. The complexes also exhibit quasi-reversible oxidations at low anodic potentials, thus modeling the structure, dynamics, and redox reactivity of the reduced NiSOD active site.
创建时间：
2008-09-15
