Arylation of Rhodium(II) Azavinyl Carbenes with Boronic Acids
收藏NIAID Data Ecosystem2026-03-07 收录
下载链接：
https://figshare.com/articles/dataset/Arylation_of_Rhodium_II_Azavinyl_Carbenes_with_Boronic_Acids/2487373
下载链接
链接失效反馈官方服务：
资源简介：
A highly efficient and stereoselective arylation of in
situ-generated
azavinyl carbenes affording 2,2-diaryl enamines at ambient temperatures
has been developed. These transition-metal carbenes are directly produced
from readily available and stable 1-sulfonyl-1,2,3-triazoles in the
presence of a rhodium carboxylate catalyst. In several cases, the
enamines generated in this reaction can be cyclized into substituted
indoles employing copper catalysis.
创建时间：
2012-09-12
