A Formal Total Synthesis of (±)-Kopsihainanine A Using a Raney-Cobalt Mediated Reductive Cyclization Route to Polyhydroquinolines
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https://figshare.com/articles/dataset/A_Formal_Total_Synthesis_of_-Kopsihainanine_A_Using_a_Raney-Cobalt_Mediated_Reductive_Cyclization_Route_to_Polyhydroquinolines/3503423
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资源简介：
Perhydroquinoline 4, the product of a Raney-cobalt
mediated reductive cyclization reaction, was readily converted into
the cis-ring-fused perhydroquinoline 15 that could be epimerized to its trans-fused counterpart 2 on sequential treatment with iodosylbenzene then sodium
borohydride. Tetracycle 2 is an advanced intermediate
associated with a recently reported total synthesis of the alkaloid
kopsihainanine A (1).
创建时间：
2016-08-29
