Silver and Palladium Complexes of a Bis(benzimidazolin-2-ylidene)pyridine Pincer Ligand
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https://figshare.com/articles/dataset/Silver_and_Palladium_Complexes_of_a_Bis_benzimidazolin_2_ylidene_pyridine_Pincer_Ligand/2869708
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资源简介：
Reaction of 2,6-bis(3-butylbenzimidazol-1-ium)pyridine dibromide with silver oxide affords a dinuclear complex of the type [L2Ag2]2+ [L = 2,6-bis(3-butylbenzimidazolin-2-ylidene)pyridine]. 1H NMR spectroscopic studies suggest that the dinuclear structure is also present in solution. Transmetalation of the silver-NHC complex with PdCl2(CH3CN)2 yields a mononuclear palladium complex of the type [LPdCl]+, with a chelating C,N,C pincer ligand.
创建时间：
2016-02-26
