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Microclimate and soil-type effects on chlorpyrifos degradation kinetics in tropical agricultural soils

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Zenodo2025-12-07 更新2026-05-26 收录
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This dataset supports the article “Microclimate and soil-type effects on chlorpyrifos degradation kinetics in tropical agricultural soils.” It includes the raw degradation data, microclimate measurements, and representative chromatograms used to validate analytical selectivity. Contents: Figure3_Chlorpyrifos_Degradation.xlsx – daily concentrations (mg·kg⁻¹) for Ultisol and peat soils under light and dark conditions. DATA Temperature, RH, Intensity.xlsx – daily microclimate measurements. Figure 5_full_intervals_DSI.csv – interval-based rate constants (k̂) and Dry–Sunny Index (DSI) values. Sampel C0H0 (I,II) gambut.pdf and Sampel C0H0 (I,II) mineral.pdf – GC–FPD chromatograms confirming selectivity at day 0 for both soils in the dark condition. The dataset promotes transparency of the kinetic modeling presented in the manuscript but does not include chromatograms for all time points because the analytical protocol is designed to quantify only the parent chlorpyrifos compound using phosphorus-mode FPD.

本数据集支持学术论文《热带农业土壤中微气候与土壤类型对毒死蜱(chlorpyrifos)降解动力学的影响》,包含用于验证分析选择性的原始降解数据、微气候实测数据与代表性色谱图。 数据集内容如下: 1. Figure3_毒死蜱降解.xlsx:老成土(Ultisol)与泥炭土(peat soil)在光照、黑暗条件下的每日浓度数据(mg·kg⁻¹)。 2. DATA 温度、相对湿度(RH)、光照强度.xlsx:每日微气候实测数据。 3. Figure 5_full_intervals_DSI.csv:基于时段的速率常数(k̂)与晴旱指数(DSI)数值。 4. Sampel C0H0 (I,II) gambut.pdf 与 Sampel C0H0 (I,II) mineral.pdf:暗培养第0天时两种土壤样品的气相色谱-火焰光度检测器(GC-FPD)色谱图,用于验证分析选择性。 本数据集旨在提升该论文稿中动力学建模研究的透明度,但由于分析方案仅采用磷模式火焰光度检测器对母体毒死蜱化合物进行定量,因此未包含所有时间节点的色谱图。

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Zenodo
创建时间:
2025-12-07
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