Synthesis of Naphthalene Amino Esters by the Blaise Reaction of <i>o</i>‑Alkynylarenenitriles
收藏NIAID Data Ecosystem2026-03-08 收录
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The action of a Reformatsky reagent on o-alkynylarenenitriles provides a convenient access to naphthalene amino esters via tandem 6-endo-dig carbannulation of in situ generated Blaise reaction intermediates. The products are formed in moderate to good yields with high chemo- and regioselectivity.
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2016-02-17
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