Dehydrogenative [4 + 2] Cycloaddition of Formamides with Alkynes through Double C−H Activation
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https://figshare.com/articles/dataset/Dehydrogenative_4_2_Cycloaddition_of_Formamides_with_Alkynes_through_Double_C_H_Activation/2682949
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资源简介：
Formamides having 1-arylalkyl groups on nitrogen undergo an unprecedented dehydrogenative [4 + 2] cycloaddition reaction with alkynes via nickel/AlMe3 cooperative catalysis to give highly substituted dihydropyridone derivatives in good yields. Notably, the transformation proceeds through double functionalization of C(sp2)−H and C(sp3)−H bonds in the formamides.
创建时间：
2016-02-23
