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Heterotriangulenes π‑Expanded at Bridging Positions

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NIAID Data Ecosystem2026-03-08 收录
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A series of nitrogen-containing heterotriangulenes expanded at the bridging positions has been synthesized. Among them, a dibenzo­[c,g]­fluorenylidene-substituted derivative has a highly twisted conformation for the overcrowded alkene moieties, which impart a highly electron-accepting character to the electron-donating heterotriangulene skeleton and thereby an NIR absorption as well as multiredox properties with a low reduction potential.

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2016-02-17
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