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Multifunctional Anthracene-Based Ni-MOF with Encapsulated Fullerenes: Polarized Fluorescence Emission and Selective Separation of C<sub>70</sub> from C<sub>60</sub>
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下载链接：
https://figshare.com/articles/dataset/Multifunctional_Anthracene-Based_Ni-MOF_with_Encapsulated_Fullerenes_Polarized_Fluorescence_Emission_and_Selective_Separation_of_C_sub_70_sub_from_C_sub_60_sub_/17705467
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资源简介：
We
report an anthracene-based Ni-MOF [Ni(II) metal–organic
framework, {[Ni(μ2-L)2Cl2]·x(C6H6)·y(MeOH)}n (1), L = anthracene-9,10-diylbis(methylene)diisonicotinate] whose
crystal structure reveals the presence of hexagonal channels with
a pore size of 1.4 nm that can accommodate guests such as C60 and C70. Both confocal fluorescence and Raman microscopy
results are in agreement with a homogeneous distribution of fullerenes
throughout the single crystals of 1. Efficient energy
transfer from 1 to the fullerenes was observed, which
emitted partially polarized fluorescence emission. Stronger binding
between 1 and C70 versus C60 was
confirmed from HPLC analysis of the dissolved material and provides
a basis for the selective retention of C70 in liquid chromatography
columns packed with 1.
创建时间：
2021-12-30
