The Influence of Amine Functionalities on Anion Binding in Polyamide-Containing Macrocycles
收藏NIAID Data Ecosystem2026-03-06 收录
下载链接：
https://figshare.com/articles/dataset/The_Influence_of_Amine_Functionalities_on_Anion_Binding_in_Polyamide_Containing_Macrocycles/2834275
下载链接
链接失效反馈官方服务：
资源简介：
Mixed amide/amine macrocyclic anion hosts of varying sizes and with different amine substituents have been synthesized and characterized. Host 2, containing a 28-membered ring and secondary amines, has shown selective binding for HSO4− over other oxo anions and halides in DMSO-d6 using NMR titrations. Crystal structures of SO42−, HPO42−, H2PO4−, and H2P2O72− with the 28-membered ring hosts indicate different macrocyclic conformations depending on the N-substituent. Anion affinities appear to be correlated with macrocycle conformation.
创建时间：
2016-02-26
