Well-Defined Butadienyl Organocopper(I) Aggregates from Zirconacyclopentadienes and CuCl: Synthesis and Structural Characterization
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https://figshare.com/articles/dataset/Well_Defined_Butadienyl_Organocopper_I_Aggregates_from_Zirconacyclopentadienes_and_CuCl_Synthesis_and_Structural_Characterization/2132401
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资源简介:
Two examples of mixed alkenyl/aryl
organocopper(I) aggregates possessing
conjugated alkenyl/aryl C–Cu bonds were synthesized by transmetalation
of zirconaindenes with CuCl. Single-crystal X-ray structural analysis
revealed tetrameric and hexameric structures. Butadienyl copper(I)
aggregates were also synthesized and structurally characterized for
further comparison. The preliminary reaction chemistry of the copper(I)
aggregates was studied.
创建时间:
2016-02-13



