η<sup>3</sup>‑Furfuryl and η<sup>3</sup>‑Thienyl Complexes of Palladium and Platinum of Relevance to the Functionalization of Biomass-Derived Furans
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A number of cationic and neutral η3-furfuryl complexes of palladium and platinum were prepared, including one with a ligand derived from fructose, 5-chloromethylfurfural. The complexes were studied by variable-temperature and heteronuclear correlation NMR spectroscopy, as well as single-crystal X-ray crystallography. Analogous η3-thienyl complexes could be prepared and detected in solution by NMR, but could not be isolated due to facile decomposition.
创建时间：
2016-02-20
