Synthesis and Structural Analysis of a Highly Curved Buckybowl Containing Corannulene and Sumanene Fragments
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https://figshare.com/articles/dataset/Synthesis_and_Structural_Analysis_of_a_Highly_Curved_Buckybowl_Containing_Corannulene_and_Sumanene_Fragments/2599558
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Buckybowls 7, 9, and 10 were prepared from benzo[k]fluoranthene 6 and fluoranthene 8 using straightforward procedures involving key palladium-catalyzed cyclization reactions. The structures of bowl-shaped molecules 7 and 10 were determined by using X-ray crystallographic methods. The observed p-orbital axis vector (POAV) angle of 7 was found to be 12.8°.
创建时间：
2016-02-22
