(Z)‑Selective Hydrosilylation of Terminal Alkynes with HSiMe(OSiMe3)2 Catalyzed by a Ruthenium Complex Containing an N‑Heterocyclic Carbene
收藏Figshare2018-09-08 更新2026-04-29 收录
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https://figshare.com/articles/dataset/_i_Z_i_Selective_Hydrosilylation_of_Terminal_Alkynes_with_HSiMe_OSiMe_sub_3_sub_sub_2_sub_Catalyzed_by_a_Ruthenium_Complex_Containing_an_N_Heterocyclic_Carbene/5389267
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资源简介：
The N-heterocyclic-carbene-ligated ruthenium complex [RuHCl(CO)(H2IMes)(PCy3)] exhibits high catalytic activity for the (Z)-selective hydrosilylation of various terminal alkynes with 1,1,1,3,5,5,5-heptamethyltrisiloxane (HSiMe(OSiMe3)2). The stereoretentive derivatization of the (Z)-alkenylsiloxanes allows the synthesis of biologically active compounds, e.g. potent antitumor agents and inhibitors for induced-NO synthase.
创建时间：
2018-09-08
