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Catalytic Decarboxylative Alkenylation of Enolates

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Figshare2016-02-19 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Catalytic_Decarboxylative_Alkenylation_of_Enolates/2395072
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A palladium-catalyzed decarboxylative alkenylation of stabilized enolates has been developed, which gives rise to alkenylated dicarbonyl products from enol carbonates regioselectively with concomitant installation of a quaternary all-carbon center. The broad scope of the reaction has been demonstrated by successfully utilizing a range of enolates and external phenol nucleophiles.
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2016-02-19
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