Synthesis and Photophysical Properties of Trimetallic Acetylide Complexes with a 1,3,5-Triazine Core
收藏NIAID Data Ecosystem2026-03-06 收录
下载链接：
https://figshare.com/articles/dataset/Synthesis_and_Photophysical_Properties_of_Trimetallic_Acetylide_Complexes_with_a_1_3_5_Triazine_Core/3275137
下载链接
链接失效反馈官方服务：
资源简介：
Treatment of 2,4,6-tris(4-bromophenyl)-1,3,5-triazine (2,4,6-(4-BrC6H4)3-1,3,5-C3N3)with
HC⋮CSiMe3in the presence of Pd(PPh3)4/CuI and NEt3 produces 2,4,6-[4-(Me3SiC⋮C)C6H4]3-1,3,5-C3N3, which reacts with Bu4NF to yield 2,4,6-[4-(HC⋮C)C6H4]3-1,3,5-C3N3. Reaction
of 2,4,6-[4-(HC⋮C)C6H4]3-1,3,5-C3N3 with AuCl(PPh3) in the presence of NEt3 produces the
gold acetylide complex 2,4,6-[4-((PPh3)AuC⋮C)C6H4]3-1,3,5-C3N3. Treatment of 2,4,6-[4-(HC⋮C)C6H4]3-1,3,5-C3N3 with cis-RuCl2(dppe)2/NaPF6 followed by NEt3 gives 2,4,6-[4-(Cl(dppe)2RuC⋮C)C6H4]3-1,3,5-C3N3, which reacts with p-HC⋮CC6H4R (R = OCH3, NO2) to give
2,4,6-[4-((4-RC6H4C⋮C)(dppe)2RuC⋮C)C6H4]3-1,3,5-C3N3. The electrochemical and photophysical properties of the new complexes have been investigated.
创建时间：
2005-08-01
