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Enantioselective Synthesis of Cyclobutenes by Intermolecular [2+2] Cycloaddition with Non‑C2 Symmetric Digold Catalysts

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Figshare2017-11-09 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Enantioselective_Synthesis_of_Cyclobutenes_by_Intermolecular_2_2_Cycloaddition_with_Non_i_C_i_sub_2_sub_Symmetric_Digold_Catalysts/5433463
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The enantioselective intermolecular gold­(I)-catalyzed [2+2] cycloaddition of terminal alkynes and alkenes has been achieved using non-C2-chiral Josiphos digold­(I) complexes as catalysts, by the formation of the monocationic complex. This new approach has been applied to the enantioselective total synthesis of rumphellaone A.
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2017-11-09
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