Lewis Base Character of Hydroxygermylenes for the Preparation of Heterobimetallic LGe(OH)M Systems (M = Fe, Mn, L = HC[(CMe)(NAr)]<sub>2</sub>, Ar = 2,6-<i>i</i>Pr<sub>2</sub>C<sub>6</sub>H<sub>3</sub>)
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LGeOH (1; L = HC[(CMe)(NAr)]2, Ar = 2,6-iPr2C6H3) reacted with iron and manganese complexes to give LGe(OH)Fe(CO)4 (2) and LGe(OH)Mn(Cp)(CO)2 (3; Cp = cyclopentadienyl). Compounds 2 and 3 were characterized by IR, multinuclear NMR, EI-MS, and single-crystal X-ray diffraction.
创建时间：
2016-05-05
