A Simple and Efficient Copper-Catalyzed Procedure for the Hydrosilylation of Hindered and Functionalized Ketones
收藏NIAID Data Ecosystem2026-03-06 收录
下载链接：
https://figshare.com/articles/dataset/A_Simple_and_Efficient_Copper_Catalyzed_Procedure_for_the_Hydrosilylation_of_Hindered_and_Functionalized_Ketones/3282652
下载链接
链接失效反馈官方服务：
资源简介：
The catalytic hydrosilylation of highly hindered and functionalized ketones is described. The
combination of inexpensive catalyst precursors, CuCl and NHC·HX (NHC = N-heterocyclic carbene),
leads to a highly efficient reduction mediator for the preparation of silyl ethers from unfunctionalized
and functionalized alkyl, cyclic, bicyclic, aromatic, and heteroaromatic ketones. A series of catalyst
precursors have been structurally characterized and a catalyst−structure activity relationship is
discussed.
创建时间：
2016-05-06
