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Cascade Carbopalladation Reaction between Alkynes and gem-Dibromoolefins: Facile Access to Monoannelated Pentalenes

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Figshare2016-02-20 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Cascade_Carbopalladation_Reaction_between_Alkynes_and_i_gem_i_Dibromoolefins_Facile_Access_to_Monoannelated_Pentalenes/2495512
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A carbopalladation cascade reaction of easily accessible gem-dibromoolefins and alkynes furnishes monobenzo- and mononaphthopentalenes. The new chromophores accessed by this short route exhibit small HOMO–LUMO gaps and redox amphoteric behavior with tunable redox potentials.
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2016-02-20
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