Formal Synthesis of (±)-Pentalenolactone A Methyl Ester
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https://figshare.com/articles/dataset/Formal_Synthesis_of_-Pentalenolactone_A_Methyl_Ester/9098096
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资源简介：
We
report the formal synthesis of (±)-pentalenolactone A methyl
ester from simple 2-methoxyphenol. The key features of our route are
as follows: a Diels–Alder reaction of masked o-benzoquinone to assemble the functionalized bicyclo[2.2.2]octenone,
a continuous-flow oxa-di-π-methane rearrangement for building
the diquinane core (AB ring), and an oxidative cleavage/oxidation
sequence for annulation of the δ-lactone (C ring).
创建时间：
2019-07-12
