A Base-Stabilized Silyliumylidene Cation as a Ligand for Rhodium and Tungsten Complexes
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下载链接：
https://figshare.com/articles/dataset/A_Base_Stabilized_Silyliumylidene_Cation_as_a_Ligand_for_Rhodium_and_Tungsten_Complexes/2274739
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资源简介：
The reaction of the base-stabilized
silyliumylidene triflate [LSi(DMAP)]OTf
(1·OTf; L = PhC(NtBu)2, DMAP = 4-dimethylaminopyridine) with [Rh(cod)Cl]2 and W(CO)5THF afforded [{L(DMAP)Si}2{μ-Rh(μ-Cl)2Rh(cod)}](OTf)2 (2) and [L(DMAP)Si→W(CO)5]OTf (3), respectively. Their crystal structures determined by X-ray crystallography show
that the silyliumylidene cation acts as a two-electron donor coordinating
to the rhodium and tungsten atoms.
创建时间：
2014-07-14
