Replication Data for: Conformational tuning improves the stability of spirocyclic nitroxides with long paramagnetic relaxation times

Name: Replication Data for: Conformational tuning improves the stability of spirocyclic nitroxides with long paramagnetic relaxation times
Creator: UiT The Arctic University of Norway; SUPA, School of Physics and Astronomy and BSRC, University of St Andrews, North Haugh, St Andrews, KY16 9SS, UK
Published: 2022-01-01T00:00:00+08:00

DataverseNO2023-09-28 更新2026-04-13 收录

电子顺磁共振

氮氧自由基稳定性

数据链接：

https://dataverse.no/citation?persistentId=doi:10.18710/UQMMZE 数据链接链接失效反馈

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资源简介：

Nitroxides are widely used as probes and polarization transfer agents in spectroscopy and imaging.These applications require high stability towards reducing biological environments, as well as beneficial relaxation properties. Closed spirocyclohexyl nitroxides exhibit a dramatically improved stability towards reduction by ascorbate, while maintaining long relaxation times in EPR spectroscopy. This dataset contains raw files and analysis reports of 1HNMR, 13CNMR, HRMS, FTIR of all compounds synthesized for and used in work: Conformational tuning improves the stability of spirocyclic nitroxides with long paramagnetic relaxation times. Moreover, for nitroxides raw files of X-band CW-EPR spectra, kinetic runs based on CW-EPR spectra and Q-band EPR relaxation measurements are included. Dataset is completed with X-ray crystallography CIF files and reports, as well as all optimized geometries for discussed conformers

提供机构：

UiT The Arctic University of Norway; SUPA, School of Physics and Astronomy and BSRC, University of St Andrews, North Haugh, St Andrews, KY16 9SS, UK

创建时间：

2022-01-01