Hg(OTf)2 Catalyzed Intramolecular 1,4-Addition of Donor–Acceptor Cyclopropenes to Arenes
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https://figshare.com/articles/dataset/Hg_OTf_sub_2_sub_Catalyzed_Intramolecular_1_4_Addition_of_Donor_Acceptor_Cyclopropenes_to_Arenes/2134987
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A Hg(OTf)2 catalyzed intramolecular arene 1,4-addition reaction of N-benzyl donor–acceptor cyclopropenecarboxamides was developed to synthesize a series of [3.2.2]nonatriene derivatives. This novel reaction is also observed with silver(I) catalysts known to form metal carbene intermediates in competition with the Buchner reaction.
创建时间：
2016-02-13
