One-Dimensional <i>μ</i>-Chloromanganese(II)−Tetrathiafulvalene (TTF) Coordination Compound
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资源简介:
A new tetrathiafulvalene derivative 1 bearing a single pyridine group and its coordination complex 2, with stoichiometry [Mn(μ-Cl)Cl(1)2(CH3OH)]n, have been synthesized and fully characterized. The complex 2 shows an extended chain structure, which is potentially favorable for electrical conductivity. Notably, this is the first monohalogen-bridged Mn(II) polymer exhibiting a moderate antiferromagnetic coupling between the Mn(II) centers.
创建时间:
2016-05-05



