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One-Dimensional <i>μ</i>-Chloromanganese(II)−Tetrathiafulvalene (TTF) Coordination Compound

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NIAID Data Ecosystem2026-03-06 收录
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A new tetrathiafulvalene derivative 1 bearing a single pyridine group and its coordination complex 2, with stoichiometry [Mn(μ-Cl)Cl(1)2(CH3OH)]n, have been synthesized and fully characterized. The complex 2 shows an extended chain structure, which is potentially favorable for electrical conductivity. Notably, this is the first monohalogen-bridged Mn(II) polymer exhibiting a moderate antiferromagnetic coupling between the Mn(II) centers.

创建时间:
2016-05-05
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