Phosphine Control of the Oxidative Addition Chemistry of Tetrathiocins to Palladium(0): Characterization of Mono‑, Di‑, and Hexanuclear Palladium(II) Dithiolate Complexes
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https://figshare.com/articles/dataset/Phosphine_Control_of_the_Oxidative_Addition_Chemistry_of_Tetrathiocins_to_Palladium_0_Characterization_of_Mono_Di_and_Hexanuclear_Palladium_II_Dithiolate_Complexes/2125690
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资源简介：
The
outcome of the oxidative addition reactions of bis(4′,5′-dimethoxybenzo)-1,2,5,6-tetrathiocin
to Pd2dba3 under microwave conditions is sensitive
to the nature of the phosphine coreagent; the bidentate phosphines
dppm, dppe, and dppf afford the mononuclear dithiolates (dmobdt)Pd(dppm)
(4), (dmobdt)Pd(dppe) (2), and (dmobdt)Pd(dppf)
(5), whereas more labile monodentate phosphines lead
to aggregation; Ph3P afforded the dinuclear dithiolate
(dmobdt)2Pd2(PPh3)2 (6), whereas tBu3P generated
the phosphine-free hexanuclear edge-capped octahedral complex Pd6(dmobdt)6 (7) [dmobdt = 4,5-dimethoxybenzenedithiolate,
(MeO)2C6H2S22–].
创建时间：
2016-02-12
