Enantioselective Nickel-Catalyzed Hydrocyanative Desymmetrization of Norbornene Derivatives
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https://figshare.com/articles/dataset/Enantioselective_Nickel-Catalyzed_Hydrocyanative_Desymmetrization_of_Norbornene_Derivatives/14755425
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A nickel-catalyzed enantioselective hydrocyanation of N-aryl 5-norbornene-endocis-2,3-dicarboximides was reported. This desymmetrization process allows for a quick construction of both continuous stereogenic carbon centers and remote N–CAr atropisomeric chirality. Mechanism studies indicated that the resident carbonyl group of the substrates plays a key role in the enantioselectivity.
创建时间：
2021-06-09
