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Synthesis of 6‑Phosphorylated Phenanthridines by Mn(II)-Promoted Tandem Reactions of 2‑Biaryl Isothiocyanates with Phosphine Oxides

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Figshare2017-06-21 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Synthesis_of_6_Phosphorylated_Phenanthridines_by_Mn_II_-Promoted_Tandem_Reactions_of_2_Biaryl_Isothiocyanates_with_Phosphine_Oxides/5132290
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资源简介:
A novel Mn­(II)-promoted tandem phosphorylation/cyclization reaction of 2-biaryl isothiocyanates with phosphine oxides is described. This is the first general method to synthesize 6-phosporylated phenanthridines from 2-biaryl isothiocyanates. The approach is featured by oxidant-free, low loading of P-reagent, easy operation, and high functional group tolerance.
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2017-06-21
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