Reductive CO2 Fixation via Tandem C–C and C–N Bond Formation: Synthesis of Spiro-indolepyrrolidines
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https://figshare.com/articles/dataset/Reductive_CO_sub_2_sub_Fixation_via_Tandem_C_C_and_C_N_Bond_Formation_Synthesis_of_Spiro-indolepyrrolidines/5278249
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We describe herein a tandem C–C and C–N bond-forming reaction in the reductive functionalization of CO2, an abundant and cheap C1 chemical feedstock. This catalytic metal-free CO2 fixation afforded spiro-indolepyrrolidines by dearomatization of tryptamine derivatives with broad scope and good functional group tolerance under mild conditions.
创建时间:
2017-08-04



