Syntheses and Structures of Distibene Complexes of Tungsten and Titanium: [W(CO)5{(2,6-Mes2C6H3)2Sb2}] (Mes = 2,4,6-Me3C6H2) and [Cp2Ti{(2,6-Mes2C6H3)2Sb2)}]
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https://figshare.com/articles/dataset/Syntheses_and_Structures_of_Distibene_Complexes_of_Tungsten_and_Titanium_W_CO_sub_5_sub_2_6-Mes_sub_2_sub_C_sub_6_sub_H_sub_3_sub_sub_2_sub_Sb_sub_2_sub_Mes_2_4_6-Me_sub_3_sub_C_sub_6_sub_H_sub_2_sub_and_Cp_sub_2_sub_Ti_2_6-Mes_sub_2_sub_C_/12068085
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Exposure of [W(CO)5(2,6-Mes2C6H3SbH2)] (1) in toluene to day light leads to the distibene complex [W(CO)5{(2,6-Mes2C6H3)2Sb2}] (2). [Cp2Ti{(2,6-Mes2C6H3)2Sb2}] (3) is obtained by reaction of [Cp2Ti{(Me3Si)2C2}] with 2,6-Mes2C6H3SbH2. The structures of 2 and 3 were determined by single-crystal X-ray diffraction, and DFT calculations were carried out on Me2Sb2, [W(CO)5(Me2Sb2)] (2a), and [Cp2Ti(Me2Sb2)] (3a).
创建时间：
2007-10-22
