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Facile Construction of a Novel Aminoquinazolinate Anionic Ligand through Organolanthanide-Mediated Intermolecular Nucleophilic Addition/Cyclization of Anthranilonitrile

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NIAID Data Ecosystem2026-03-06 收录
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https://figshare.com/articles/dataset/Facile_Construction_of_a_Novel_Aminoquinazolinate_Anionic_Ligand_through_Organolanthanide_Mediated_Intermolecular_Nucleophilic_Addition_Cyclization_of_Anthranilonitrile/2929555
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资源简介:
Compounds Cp2Ln[κ3-(4-NH(C8N2H4)(2-NH2C6H4)] [Cp = C5H5; Ln = Er (1), Y (2)] were synthesized by the reaction of Cp2LnNiPr2(THF) with anthranilonitrile, indicating a novel organolanthanide-mediated intermolecular nucleophilic addition/cyclization of anthranilonitrile. To trap the intermediate I, a probe reaction of Cp2ErNiPr2(THF) with anthranilonitrile and carbodiimide has also been investigated.
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2016-02-27
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