Copper-Catalyzed Ring Expansion of Cyclopropyl Ketones/Formation of N‑acyliminium/Hetero-[4 + 2]-Cycloaddition: A Route to Substituted Pentacyclic Isoindolin-1-one
收藏Figshare2018-07-02 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Copper-Catalyzed_Ring_Expansion_of_Cyclopropyl_Ketones_Formation_of_i_N_i_acyliminium_Hetero-_4_2_-Cycloaddition_A_Route_to_Substituted_Pentacyclic_Isoindolin-1-one/6734879
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资源简介：
A Cu-catalyzed three-component cascade cyclization among 2-formylbenzonitrile, cyclopropyl ketones, and diaryliodonium salts for the construction of fused isoindolin-1-one compounds is achieved. Pentacyclic isoindolinone derivatives could be obtained in moderate to good yields. The proposed mechanism involved a ring expansion of cyclopropyl ketones/formation of N-acyliminium/hetero-[4 + 2]-cycloaddition process.
创建时间：
2018-07-02
