Palladium-Catalyzed Olefin Dioxygenation
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https://figshare.com/articles/dataset/Palladium_Catalyzed_Olefin_Dioxygenation/2952190
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资源简介：
A general method for the vicinal dioxygenation of olefins was developed using cationic Pd diphosphine complexes as the catalysts and PhI(OAc)2 as the terminal oxidant. In comparison to known Pd-catalyzed vicinal oxidations, this method is suitable for a broad range of olefins in both inter- and intramolecular reactions. An 18O-labeling experiment provides insight into the mechanism of this transformation which presumably involves Pd(II)/Pd(IV) intermediates.
创建时间：
2016-06-03
