遇见数据集

Dataset for the article in RPD (doi: 10.1093/rpd/ncad151)

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This is a dataset which we used to prepare Fiugres 1 to 6 (except Figure 5) in the paper "Hydrogen transfer reactions via organic radicals in gamma-irradiated chibaite" by Yokoyama, Isogai, Kusuki, Tani, and Nishido in RPD. It is an 'Excel' file with 6 sheets. The followings are brief description for them. The detailed information is in the paper. #1 Figure 1 ESR spectrum in Fig1-a and Fig1-b. #2 Figure 2a ESR spectrum in Fig2-a. #3 Figure 2b ESR spectrum in Fig2-b. #4 Figure 3 Variation in the amounts of the organic radicals and hydrogen atoms in isothermal annealing experiments at 240 K. #5 Figure 4 Variation in the amount of the tert-butyl radical (solid triangle) and the combined amount of ethyl and isopropyl radicals (solid square) in isothermal annealing experiments at 240 K. The open square in the upper part indicates the variation of the three organic radicals with the same conditions. #6 Figure 6 Arrhenius plot of the decay of the total amount of ethyl and isopropyl radicals.

本数据集用于制备Yokoyama、Isogai、Kusuki、Tani与Nishido发表于RPD的论文"Hydrogen transfer reactions via organic radicals in gamma-irradiated chibaite"中除图5外的图1至图6。本数据集为含6个工作表的Excel文件,以下为各工作表的简要说明,详细信息请参见该论文。 #1 图1:包含图1-a与图1-b的电子自旋共振(ESR)谱图。 #2 图2a:包含图2-a的电子自旋共振谱图。 #3 图2b:包含图2-b的电子自旋共振谱图。 #4 图3:240 K恒温退火实验中有机自由基与氢原子的含量变化情况。 #5 图4:240 K恒温退火实验中叔丁基自由基(实心三角标记)、乙基与异丙基自由基总含量(实心方块标记)的变化情况;图上方的空心方块标记则代表相同实验条件下三种有机自由基的含量变化。 #6 图6:乙基与异丙基自由基总含量衰减的阿伦尼乌斯图(Arrhenius plot)。

创建时间:
2023-05-04
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