Pyridonate-Supported Titanium(III). Benzylamine as an Easy-To-Use Reductant
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https://figshare.com/articles/dataset/Pyridonate_Supported_Titanium_III_Benzylamine_as_an_Easy_To_Use_Reductant/2118226
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资源简介：
The
reaction of bis(3-phenyl-2-pyridonate)Ti(NMe2)2 with excess benzylamine leads to an unexpected reduction
of the metal center from Ti(IV) to Ti(III). The reduced titanium species
was isolated and revealed as tris(3-phenyl-2-pyridonate)Ti(NH2Bn)2. Ammonia and N-benzyl-1-phenylmethanimine
are released as byproducts of the reaction, thereby confirming benzylamine
as a mild reductant. This new pyridonate-supported titanium(III) complex
has been fully characterized, and experimental data and theoretical
calculations confirm a d1 metal center with no ligand-based
radical character. This Ti(III) complex does not react with aminoalkenes,
suggesting that radical species are not viable intermediates for the
hydroaminoalkylation or hydroamination reaction.
创建时间：
2016-02-12
