Data_Sheet_3_Palladium and Platinum 2,4-cis-amino Azetidine and Related Complexes.ZIP

Seven N,N'-palladium(II) chloride complexes, one N,N'-palladium(II) acetate complex of 2,4-cis-azetidines where prepared and analyzed by single crystal XRD. Two platinum(II) chloride N,N'-complexes of 2,4-cis-azetidines where prepared and analyzed by single crystal XRD. Computational analysis and determination of the %Vbur was examined conducted. A CNN' metallocyclic complex was prepared by oxidative addition of palladium(0) to an ortho bromo 2,4-cis-disubstituted azetidine and its crystal structure displays a slightly pyramidalized metal-ligand orientation.本研究合成并通过单晶X射线衍射（Single Crystal X-ray Diffraction，XRD）分析了7个基于2,4-顺式氮杂环丁烷的N,N'-配位氯化钯(II)配合物与1个该类配体的N,N'-配位乙酸钯(II)配合物；此外，合成并通过单晶X射线衍射分析了2个基于2,4-顺式氮杂环丁烷的N,N'-配位氯化铂(II)配合物。本研究同时开展了计算分析，并对%Vbur进行了测定。通过将零价钯与邻位溴代2,4-顺式二取代氮杂环丁烷发生氧化加成反应，制备了一种CNN'型金属环配合物，其晶体结构显示金属-配体取向呈轻微锥型化。