Facile C–H, C–F, C–Cl, and C–C Activation by Oxatitanacyclobutene Complexes
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https://figshare.com/articles/dataset/Facile_C_H_C_F_C_Cl_and_C_C_Activation_by_Oxatitanacyclobutene_Complexes/2132287
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Aryl ketones react readily with oxatitanacyclobutenes bearing pentamethylcyclopentadienyl ligands to form unique titanocene complexes resulting from Cp* modification and C–H activation. An intermediate in this reaction is intercepted with various functional groups to form carbonyl insertion, C–F activation, and cyclopropane ring-opening products.
创建时间：
2016-02-13
