Bent N‑Heteroarenes

The syntheses and optical, electronic, and structural properties of a series of bent N-heteroarenes are described. The targets were obtained by condensation reactions of substituted aromatic o-diamines with 1,2-naphthoquinone and 1,2-anthraquinone in yields between 34 and 94%; naphthoquione-based products are generally formed in higher yields.本文报道了一系列弯折型氮杂芳烃（bent N-heteroarenes）的合成方法，及其光学、电子与结构性质。目标产物通过取代芳香邻二胺与1,2-萘醌（1,2-naphthoquinone）、1,2-蒽醌（1,2-anthraquinone）的缩合反应制备得到，产率介于34%至94%之间；以1,2-萘醌为底物的产物通常可获得更高产率。