Contains Table A 1H and 13C NMR data for Compounds 1–4 and 6.
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Fig A 1H NMR spectra of F7 fraction, and authentic Lyso-PAF (9Z)-C18:1. Fig B 13C NMR spectra of F7 fraction, and authentic Lyso-PAF (9Z)-C18:1 and cis-5-dodecenoic acid. Fig C DQF-COSY spectrum of F7 fraction. Fig D TOCSY spectrum of F7 fraction. Fig E NOESY spectrum of F7 fraction. Fig F HSQC spectrum of F7 fraction. Fig G HSQC-TOCSY spectrum of F7 fraction. Fig H 1H-13C HMBC spectrum of F7 fraction. Fig I 1H-31P HMBC spectrum of F7 fraction. Fig J Base peak ion chromatograms and mass chromatograms on LC/TOF-MS. Fig K Mass spectrum for RT 5.83 of F7 fraction, Lyso-PAF C18:0 (1). Fig L Mass spectrum for RT 4.95 of F7 fraction, Lyso-PAF (11Z)-C18:1 (2). Fig M Mass spectrum for RT 5.57 of F7 fraction, LPC C18:0 (3) Fig N Mass spectrum for RT 4.49 of F7 fraction, LPC C16:0 (4) Fig O Mass spectrum for RT 4.76 of F7 fraction, Lyso-PAF C16:0 (5). Fig P Mass spectrum for RT 6.23 of F7 fraction, Lyso-PAF 17’- Methyl-C18:0 (6). Fig Q Mass spectrum for Lyso-PAF C18:0 (1) of a standard mixture. Fig R Mass spectrum for Lyso-PAF (9Z)-C18:1 of a standard mixture. Fig S Mass spectrum for LPC C18:0 (3) of a standard mixture. Fig T Mass spectrum for LPC C16:0 (4) of a standard mixture. Fig U Mass spectrum for LPC (9Z)-C18:1 of a standard mixture. Fig V Mass spectrum for RT 0.70 of ozonolysis products, C11-carboxylic acid (7). Fig W Mass spectrum for RT 0.78 of ozonolysis products, C11-aldehyde (8). Fig X Mass spectrum for RT 1.01 of ozonolysis products, C11-d6-dimethyl acetal (9).
(PDF)
图A:F7组分的1H核磁共振(1H NMR)谱,以及对照品溶血血小板活化因子(Lyso-PAF)(9Z)-C18:1的谱图;图B:F7组分的13C核磁共振(13C NMR)谱,以及对照品溶血血小板活化因子(Lyso-PAF)(9Z)-C18:1和顺式-5-十二碳烯酸的谱图;图C:F7组分的双量子滤波相干谱(DQF-COSY);图D:F7组分的全相关谱(TOCSY);图E:F7组分的核Overhauser效应谱(NOESY);图F:F7组分的异核单量子相干谱(HSQC);图G:F7组分的HSQC-TOCSY谱;图H:F7组分的1H-13C异核多键相干谱(HMBC);图I:F7组分的1H-31P异核多键相干谱(HMBC);图J:液相色谱-飞行时间质谱(LC/TOF-MS)下的基峰离子色谱图与质量色谱图;图K:F7组分在保留时间(RT)5.83处的质谱图,对应溶血血小板活化因子C18:0(1);图L:F7组分在保留时间4.95处的质谱图,对应溶血血小板活化因子(11Z)-C18:1(2);图M:F7组分在保留时间5.57处的质谱图,对应溶血磷脂酰胆碱(LPC)C18:0(3);图N:F7组分在保留时间4.49处的质谱图,对应溶血磷脂酰胆碱(LPC)C16:0(4);图O:F7组分在保留时间4.76处的质谱图,对应溶血血小板活化因子C16:0(5);图P:F7组分在保留时间6.23处的质谱图,对应溶血血小板活化因子17’-甲基-C18:0(6);图Q:标准混合物中溶血血小板活化因子C18:0(1)的质谱图;图R:标准混合物中溶血血小板活化因子(9Z)-C18:1的质谱图;图S:标准混合物中溶血磷脂酰胆碱(LPC)C18:0(3)的质谱图;图T:标准混合物中溶血磷脂酰胆碱(LPC)C16:0(4)的质谱图;图U:标准混合物中溶血磷脂酰胆碱(LPC)(9Z)-C18:1的质谱图;图V:臭氧化产物中保留时间0.70处的质谱图,对应C11-羧酸(7);图W:臭氧化产物中保留时间0.78处的质谱图,对应C11-醛(8);图X:臭氧化产物中保留时间1.01处的质谱图,对应C11-d6-二甲基缩醛(9)。(PDF)
创建时间:
2015-08-14



