Rhodium-Catalyzed Highly Enantioselective Arylation of Cyclic Diketimines: Efficient Synthesis of Chiral Tetrasubstituted 1,2,5-Thiadiazoline 1,1-Dioxides
收藏Figshare2016-02-17 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Rhodium_Catalyzed_Highly_Enantioselective_Arylation_of_Cyclic_Diketimines_Efficient_Synthesis_of_Chiral_Tetrasubstituted_1_2_5_Thiadiazoline_1_1_Dioxides/2269333
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A highly enantioselective rhodium-catalyzed arylation of cyclic diketimines with arylboronic acids was achieved under mild conditions by employing a simple, sulfinamide-based branched olefin ligand. This protocol provides an efficient access to valuable chiral tetrasubstituted 1,2,5-thiadiazoline 1,1-dioxides in high yields with excellent enantioselectivities of up to 99% ee.
创建时间：
2016-02-17
