Bonding and Reactivity in the Electronically Unsaturated Hydrogen-Bridged Dimer [Ru3(CO)8(μ3-CMe)(μ-H)2(μ3-H)]2
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https://figshare.com/articles/dataset/Bonding_and_Reactivity_in_the_Electronically_Unsaturated_Hydrogen_Bridged_Dimer_Ru_sub_3_sub_CO_sub_8_sub_sub_3_sub_CMe_H_sub_2_sub_sub_3_sub_H_sub_2_sub_/2564788
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The electronically unsaturated complex [Ru3(CO)8(μ3-CMe)(μ-H)2(μ3-H)]2 (1), viewed as a dimer of the 46-electron fragment Ru3(CO)8(μ3-CMe)(μ-H)3, is held together by delocalized bonding involving two triply bridging hydride ligands. Compound 1 exhibits a dynamic activity in solution that equilibrates two of the three types of hydride ligands. Compound 1 reacts with 1,1-bis(diphenylphosphino)methane to form the macrocyclic complex [Ru3(CO)7(μ3-CMe)(μ-H)3]2(μ-dppm)2 (3).
创建时间：
2016-02-22
